Preparation and characterization of supported PES membranes


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TOPUZ B., YILMAZ L., KALIPÇILAR H.

JOURNAL OF THE FACULTY OF ENGINEERING AND ARCHITECTURE OF GAZI UNIVERSITY, vol.34, no.1, pp.155-164, 2019 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 1
  • Publication Date: 2019
  • Doi Number: 10.17341/gazimmfd.416472
  • Journal Name: JOURNAL OF THE FACULTY OF ENGINEERING AND ARCHITECTURE OF GAZI UNIVERSITY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.155-164
  • Keywords: Polymer membrane, Gas separation, Polyethersulfone, Al2O3 support, COMPOSITE MEMBRANE, BIO-BUTANOL, SEPARATION, PERFORMANCE
  • Ankara University Affiliated: Yes

Abstract

In the present study. polyethersulfone (PES) membranes on a macroporous alumina support was prepared by solvent-deposition method to separate H-2/CH4 mixture. The membrane solution viscosities were determined in order to understand the effect of PES concentration on the formation of selective membranes over a support. Supported PES membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and single gas permeability measurements of H-2 and CH4. The membrane casting solution with 20% PES concentration provided the formation of defecdess single-layer supported membrane. At lower concentrations. the penetration of membrane casting solution into the pores of support was prevented by using intermediate layer. hence the prepared 2-layered membrane performance was improved. H-2/CH4 ideal selectivity of best membrane exhibited is 73 at 35 degrees C. which shows promise for H-2/Hydrocarbon separation.