Dispersion polymerization of L-lactide in supercritical carbon dioxide

YILMAZ M., Eğri S., YILDIZ N., Çalımlı A., Pişkin E.

Journal of Polymer Research, cilt.18, sa.5, ss.975-982, 2011 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 18 Sayı: 5
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1007/s10965-010-9497-y
  • Dergi Adı: Journal of Polymer Research
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.975-982
  • Anahtar Kelimeler: Poly(ethylene glycol), Poly(L-lactide), Ring-opening polymerization, Supercritical carbon dioxide, Triblock (A-B-A) stabilizers, ε-Caprolactone
  • Ankara Üniversitesi Adresli: Evet

Özet

Triblock (A-B-A) oligomers of ε-caprolactone (ε-CL) (A) and poly(ethylene glycol) with an average molecular weight of 400 (PEG400) (B) were synthesized with three different molecular weight in the range of 2-6 kDa by changing the ratio of PEG400/ε-CL. These oligomers were then used in dispersion polymerization of L-lactide in supercritical carbon dioxide (scCO 2 ) as stabilizers. 5% stabilizer in the polymerization recipe allowed synthesis of poly(L-lactide) (PLLA) in scCO 2 in the powder form with a weight average molecular weight of around 60 kDa with polymerization yields around 80%. Interestingly, there was almost no effect of stabilizer molecular weight on polymerization. L-lactide polymerization in scCO 2 without any stabilizer was also possible but both the PLLA molecular weight and polymerization yield were lower, and the product was as aggregates instead of powders. A stabilizer concentration of 5% in the polymerization recipe was found adequate. Further increases in the stabilizer load resulted lower molecular weights and lower yields. © 2010 Springer Science+Business Media B.V.