Crystal structure of tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) complex

ELERMAN Y., KABAK M., SVOBODA I., FUESS H., ATAKOL O.

Journal of Chemical Crystallography, cilt.25, sa.5, ss.227-230, 1995 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 25 Sayı: 5
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1007/bf01665174
  • Dergi Adı: Journal of Chemical Crystallography
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.227-230
  • Anahtar Kelimeler: SCHIFF BASE, TRENSAL, PARAMAGNETISM, HEXADENTATE LIGANDS, METAL-COMPLEXES
  • Ankara Üniversitesi Adresli: Evet

Özet

Tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) crystallizes in the monoclinic crystal system with a=7.766(2), b=25.423(5), c=13.318(5) Å, β=118.04(3)°, space group P21/c, V=2320.8(6) Å3, Z=4, and Dx=1.464 g cm-3. The center of the axially distorted octahedron is occupied by the Fe atom which is coordinated by six donor nitrogen and oxygen atoms in fac positions. The planes of coordinated atoms (N and O) with the Fe(III) atom are almost planar and the maximum elevated atom from these planes is O(1) (-0.1065 Å). © 1995 Plenum Publishing Corporation.