Crystal structure analysis of N,N′-bis(salicylidene)-2-methyl-1,2- propanediaminato-nickel(II)

Arici C., Ulku D., Atakol O., Svoboda I., Fuess H.

Crystal Research and Technology, cilt.41, sa.3, ss.304-308, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 41 Sayı: 3
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1002/crat.200510578
  • Dergi Adı: Crystal Research and Technology
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.304-308
  • Anahtar Kelimeler: crystal structure, mononuclear nickel complex, COMPLEXES, LIGANDS, NICKEL
  • Ankara Üniversitesi Adresli: Evet

Özet

In the title compound, N,N′-Bis(salicylidene)-2-methyl-1,2- propanediaminato-nickel(II), [NiC18H18N2O 2], (CCDC 235278), the NiII atom is coordinated by two iminic N and two phenolic O atoms of the N,N′-Bis(salicylidene)-2-methyl- 1,2-propanediaminate (SALPD2) ligand. The geometry of the coordination sphere around the Ni atom is distorted square-planar. Ni(II) ion, forms crystals which belong to the orthorhombic system, space group P cab, with unit cell dimensions a=l 1.5531(1), b=15.985(4), c=17.418(1) Å, V=3210.5(9) Å3. The cell contains eight molecules. The contact distance Ni...Nia between the neighbouring molecules is 4.4704(8) Å. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.