Crystal structure analysis of N,N′-bis(salicylidene)-2-methyl-1,2- propanediaminato-nickel(II)

Arici C., Ulku D., Atakol O., Svoboda I., Fuess H.

Crystal Research and Technology, vol.41, no.3, pp.304-308, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 41 Issue: 3
  • Publication Date: 2006
  • Doi Number: 10.1002/crat.200510578
  • Journal Name: Crystal Research and Technology
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.304-308
  • Keywords: crystal structure, mononuclear nickel complex, COMPLEXES, LIGANDS, NICKEL
  • Ankara University Affiliated: Yes

Abstract

In the title compound, N,N′-Bis(salicylidene)-2-methyl-1,2- propanediaminato-nickel(II), [NiC18H18N2O 2], (CCDC 235278), the NiII atom is coordinated by two iminic N and two phenolic O atoms of the N,N′-Bis(salicylidene)-2-methyl- 1,2-propanediaminate (SALPD2) ligand. The geometry of the coordination sphere around the Ni atom is distorted square-planar. Ni(II) ion, forms crystals which belong to the orthorhombic system, space group P cab, with unit cell dimensions a=l 1.5531(1), b=15.985(4), c=17.418(1) Å, V=3210.5(9) Å3. The cell contains eight molecules. The contact distance Ni...Nia between the neighbouring molecules is 4.4704(8) Å. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.