Synthesis and characterization of diorganotin(IV) complexes of Schiff hases with ONO-type donors and crystal structure of [N-(2-hydroxy-4-nitrophenyl)-3- ethoxysalicylideneiminato]diphenyltin (IV)+

Celebier M., Sahin E., Ancin N., Oeztas N. A., Oeztas S. G.

Applied Organometallic Chemistry, vol.21, no.10, pp.913-918, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 21 Issue: 10
  • Publication Date: 2007
  • Doi Number: 10.1002/aoc.1311
  • Journal Name: Applied Organometallic Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.913-918
  • Keywords: diorganotin(IV) complexes, tridentate Schiff base, spectroscopic studies, crystal structure, pi - pi interactions, X-RAY STRUCTURES, ORGANOTIN COMPOUNDS, MOLECULAR-STRUCTURE, SALICYLALDIMINE COMPLEXES, VIBRATIONAL FREQUENCIES, PMR SPECTRA, LIGANDS, SPECTROSCOPY, DICHLORIDE, DIHALIDE
  • Ankara University Affiliated: Yes

Abstract

A series of neutral complexes, namely, [N-(2-hydroxy-4-nitrophenyl)-3- hydroxysalicylideneiminato]-diphenyltin(IV) (Ia), [N-(2-hydroxy-4-nitrophenyl)- 3-methoxysalicylideneiminato]diphenyltin(IV) (IIa) and [N-(2-hydroxy-4- nitrophenyl)-3-ethoxysalicylideneiminato]diphenyltin(IV) (IIIa) were prepared by the reaction of diphenyltin dichloride on the corresponding Schiff bases. The Schiff bases were the reaction products of 2-hydroxy-4-nitroaniline and appropriate salicylaldehydes. AU the compounds were characterized by elemental analysis, 1H-NMR, 13C-NMR, IR and mass spectroscopy. Compound IlIa was also characterized by single crystal X-ray diffraction and shows a C2NO2 coordination geometry nearly half-way between a trigonal bipyramidal and square pyramidal arrangement. In the solid state, π - π interactions exist between the aniline fragments of neighbouring molecules. Copyright © 2007 John Wiley & Sons, Ltd.