Synthesis of ZIF-8 from recycled mother liquors

Demir, Nilay; TOPUZ, BERNA; YILMAZ, LEVENT; KALIPÇILAR, HALİL

doi:10.1016/j.micromeso.2014.07.052

Synthesis of ZIF-8 from recycled mother liquors

Demir N. K., TOPUZ B., YILMAZ L., KALIPÇILAR H.

MICROPOROUS AND MESOPOROUS MATERIALS, cilt.198, ss.291-300, 2014 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 198
Basım Tarihi: 2014
Doi Numarası: 10.1016/j.micromeso.2014.07.052
Dergi Adı: MICROPOROUS AND MESOPOROUS MATERIALS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.291-300
Anahtar Kelimeler: ZIF-8, MOP, Synthesis, Mother liquor, Recycling, METAL-ORGANIC FRAMEWORKS, ZEOLITIC IMIDAZOLATE FRAMEWORKS, MIXED-MATRIX MEMBRANES, ROOM-TEMPERATURE SYNTHESIS, CRYSTAL-GROWTH, SEPARATION, CRYSTALLIZATION, TRANSFORMATION, NANOCRYSTALS, DIFFRACTION
Ankara Üniversitesi Adresli: Evet

Özet

The effect of the methanol/Zn(NO3)(2) molar ratio on the particle size, BET surface area and on the rate of the crystallization have been studied. The use of excess methanol leads to a decrease in particle size and rate of crystallization. Crystals grown from solutions with methanol/Zn(NO3)(2) molar ratios of 1043 and 87 are 60 and 600 nm based on SEM images, respectively.