Zinc(II) complexes of bidentate Schiff base ligands containing methoxyphenyl and nitrophenyl groups

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Atıf İçin Kopyala

Tatar L., Ulku D., Atakol O.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.55, sa.4, ss.508-510, 1999 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 55 Sayı: 4
• Basım Tarihi: 1999
• Doi Numarası: 10.1107/s0108270198015406
• Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.508-510
• Ankara Üniversitesi Adresli: Evet

Özet

In the title compounds, bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N,O]zinc(II), [Zn(C13H9N2O3)2], and bis[2-(3-methoxyphenylnitrilomethylidyne)phenolato-N,O]zinc(II), [Zn(C14H12NO2)2], the tricilinic unit cell contains two inversion-related molecules. In both compounds, the Zn atom is in a slightly distorted tetrahedral coordination involving O and N atoms of two bidentate ligands. The dihedral angle defined by the two chelate rings is 98.09 (4)° for the methoxyphenyl complex and 98.05 (7)° for the nitrophenyl complex. The molecules are crosslinked via intermolecular hydrogen bonds.