Crystal structure analysis of Bis{(N,N '-dimethylformamide)-[mu-bis-N,N '-(2-oxybenzyl)-1,3-propanediaminato](mu-asetato)nickel(II)}nickel(II)

YILDIRIM L., Atakol O.

CRYSTAL RESEARCH AND TECHNOLOGY, vol.37, no.12, pp.1352-1359, 2002 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 37 Issue: 12
  • Publication Date: 2002
  • Journal Name: CRYSTAL RESEARCH AND TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1352-1359
  • Keywords: crystal structure, trinuclear complex, Ni-II, Schiff base, elemental analysis, thermal analysis, IR, COMPLEXES, NUCLEARITY
  • Ankara University Affiliated: No

Abstract

The title compound, a homotrinuclear Ni-II complex has been synthesized from ONNO type Schiff base reduced with the help of NaBH4. The structure of the complex, [Ni{Ni(CH3CO2) (C17H20N2O3) (C3H7NO)}(2)], was identified using elemental analysis, thermal analysis, IR spectroscopy and x-ray diffraction techniques, It was established that although some bond lengths and angles changed with respect to previous complexes, the Ni...Ni distance was approximately the same.