Bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato](N,N- dimethylform-amide)nickel(II)}cadmium(II)

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Atıf İçin Kopyala

Ulku D., Tahir M., Atakol O., NAZIR H.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.53, sa.7, ss.872-874, 1997 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 53 Sayı: 7
• Basım Tarihi: 1997
• Doi Numarası: 10.1107/s0108270197002047
• Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.872-874
• Ankara Üniversitesi Adresli: Evet

Özet

The structure of the title compound, [Cd(C2H3O2)2{Ni-(C3H 7NO)(C17H16N2O2)} 2], consists of a linear hetero-trinuclear unit with a central CdII ion. Both this ion and the terminal NiII ions have pseudo-octahedral coordination. Each pair of metal ions is triply bridged via O atoms from N,N′-bis(salicylidene)-1,3-propane-diaminato (SALPD2-) ligands and acetate groups. The coordination around the CdII ion involves four O atoms from two SALPD2- and two acetate ligands. The coordination of the NiII ion is provided by the two O and two N atoms from a SALPD2- ligand and one O atom each from an acetate and a dimethylformamide ligand. The Cd⋯Ni distance is 3.2274 (5) Å.