Bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato](N,N- dimethylform-amide)nickel(II)}cadmium(II)
Acta Crystallographica Section C: Crystal Structure Communications, cilt.53, sa.7, ss.872-874, 1997 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 53 Sayı: 7
- Basım Tarihi: 1997
- Doi Numarası: 10.1107/s0108270197002047
- Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.872-874
- Ankara Üniversitesi Adresli: Evet
Özet
The structure of the title compound, [Cd(C2H3O2)2{Ni-(C3H 7NO)(C17H16N2O2)} 2], consists of a linear hetero-trinuclear unit with a central CdII ion. Both this ion and the terminal NiII ions have pseudo-octahedral coordination. Each pair of metal ions is triply bridged via O atoms from N,N′-bis(salicylidene)-1,3-propane-diaminato (SALPD2-) ligands and acetate groups. The coordination around the CdII ion involves four O atoms from two SALPD2- and two acetate ligands. The coordination of the NiII ion is provided by the two O and two N atoms from a SALPD2- ligand and one O atom each from an acetate and a dimethylformamide ligand. The Cd⋯Ni distance is 3.2274 (5) Å.