Bis{2-[(2-hydroxybenzyl)iminomethyl]-phenolato(2-)-O:O,N,O′} dicopper(II)

Ulku, D; Ercan, F; Atakol, ORHAN; Ercan, I; Gencer, A

doi:10.1107/s0108270196012590

Bis{2-[(2-hydroxybenzyl)iminomethyl]-phenolato(2-)-O:O,N,O′} dicopper(II)

Atıf İçin Kopyala

Ulku D., Ercan F., Atakol O., Ercan I., Gencer A.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.53, sa.2, ss.179-181, 1997 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 53 Sayı: 2
Basım Tarihi: 1997
Doi Numarası: 10.1107/s0108270196012590
Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.179-181
Ankara Üniversitesi Adresli: Evet

Özet

The title compound, [Cu2(C14H11NO2)2], consists of doubly oxygen-bridged centrosymmetric copper dimers. Each Cu atom has a distorted square-planar environment involving three O atoms and an N atom of the ligands. The Cu-O distances in the coordination plane vary from 1.881 (8) to 1.930 (10) Å and the Cu-N distance is 1.920 (10) Å. In the bridging plane, the Cu-O-Cu′ and O-Cu-O′ angles are 103.5 (4) and 76.5 (3)°, respectively. The Cu⋯Cu′ distance is 3.073 (2) Å.