Structural and spectral studies of some coordination complexes of Ni(II) with N-benzylidene-2-mercaptoaniline derivatives

İDE S., Ancin N., Oztas S. G., Tuzun M.

Journal of Molecular Structure, cilt.562, sa.1-3, ss.1-9, 2001 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 562 Sayı: 1-3
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s0022-2860(00)00723-7
  • Dergi Adı: Journal of Molecular Structure
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1-9
  • Anahtar Kelimeler: NMR techniques, IR spectroscopy, X-ray studies, nickel(II) complexes
  • Ankara Üniversitesi Adresli: Evet

Özet

Nickel(II) complexes of N-(4-bromobenzylidene)-2-mercaptoaniline, N-(4-methyl benzylidene)-2-mercaptoaniline and N-(4-methoxybenzylidene)-2-mercaptoaniline were prepared and investigated. The proposed structures for these complexes derived from the two-dimensional (2-D) NMR techniques and the infrared spectra are consistent with the X-ray powder diffraction measurements and the elemental analysis results. On the other hand, energy minimization studies of the molecules were carried out to obtain the most probable molecular conformations. © 2001 Elsevier Science B.V.