(Cyclohexylamine-N){2-[(2-thiophenyl)-iminomethyl]phenolato-O,N,S} nickel(II)

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Tahir M., Ulku D., Atakol O., KENAR A.

Acta Crystallographica Section C: Crystal Structure Communications, vol.52, no.9, pp.2178-2180, 1996 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 52 Issue: 9
• Publication Date: 1996
• Doi Number: 10.1107/s0108270196006130
• Journal Name: Acta Crystallographica Section C: Crystal Structure Communications
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
• Page Numbers: pp.2178-2180
• Ankara University Affiliated: Yes

Abstract

The crystal of the title compound is composed of discrete neutral [Ni(C13H9NOS)(C6H13N)] molecules. The Ni ion has a distorted square-planar coordination. The bond distances between the Ni atom and the donor N2, S1, N1 and O1 atoms are 1.948(5), 2.148(2), 1.874(5) and 1.845 (5) Å, respectively. Although the bond angles around the Ni atom range from 83.4(2) to 96.1 (2)°, their sum is 360.1°. The cyclohexyl ring is disordered.