Pendimethalin imprinted electrochemical sensor based on CuO-Bi2MoO6 nanocomposite and pendimethalin detection in real samples


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Erbağcı M. A., Yola B. B., Özdemir N., YOLA M. L.

Microchimica Acta, cilt.193, sa.6, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 193 Sayı: 6
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1007/s00604-026-08095-3
  • Dergi Adı: Microchimica Acta
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex
  • Anahtar Kelimeler: CuO-Bi2MoO6, Molecularly imprinting polymers, Nanocomposite, Pendimethalin, Voltammetry
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • Ankara Üniversitesi Adresli: Evet

Özet

A novel approach is introduced for detection of pendimethalin (PEN) - one of the most widely utilized herbicides- based on the synergistic properties of molecularly imprinted polymers (MIPs) and a CuO-Bi2MoO6 (Cu-Bi-Mo) nanocomposite. The methodology combined the specific recognition capabilities of MIPs with the enhanced sensing performance provided by the advanced nanocomposite material. The synthesis of the Cu-Bi-Mo nanocomposite was initiated through the application of the sol-gel method. After the glassy carbon electrode’s modification with the Cu-Bi-Mo nanocomposite, PEN imprinted electrodes were fabricated using cyclic voltammetry (CV) with a dispersion containing 100.0 mM pyrrole (Py) monomer and 25.0 mM PEN molecule. The electrochemical sensor revealed a detection range of 1.0 × 10− 9 M to 1.0 × 10− 8 M PEN and achieved a detection limit (LOD) of 3.30 × 10− 10 M. To demonstrate its practical applicability, the electrochemical sensor was applied to drinking water and orange juice samples, yielding recovery results near 100%. This high recovery indicated the exceptional precision and reliability of the proposed electrochemical sensor. The electrochemical sensor’s performance was thoroughly assessed across several key metrics including selectivity, stability, and reproducibility.