Deep eutectic solvent-assisted synthesis of polyaniline by laccase enzyme

Altundag A., ÜNLÜ BÜYÜKTOPCU A. E., Takac S.

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, cilt.96, sa.4, ss.1107-1115, 2021 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 96 Sayı: 4
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1002/jctb.6626
  • Dergi Adı: JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Applied Science & Technology Source, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Computer & Applied Sciences, EMBASE, Food Science & Technology Abstracts, INSPEC, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1107-1115
  • Anahtar Kelimeler: aniline, deep eutectic solvents, laccase, polyaniline, TRAMETES-VERSICOLOR, CATALYZED SYNTHESIS, POLYMER, ACID
  • Ankara Üniversitesi Adresli: Evet

Özet

BACKGROUND Deep eutectic solvents (DESs) have attracted considerable attention for many chemical applications due to their environmentally friendly characteristics, low cost and limited or no health issues. Polyaniline (PANI) has been of a great interest for many years due to its distinctive electrical and optical properties and accordingly its diverse application fields. Enzymatic synthesis of PANI offers mild and environmentally benign conditions. However, the main difficulty of the enzymatic method is the formation of undesired units in the polymer, which can be overcome by the use of templates. Thus, the reaction is guided towards the desired products. This study reports - for the first time - that DESs can be used as templates in the synthesis of polymers.