Di-μ-acetato-bis[μ-2-hydroxy-N,N′-bis(2-oxidobenzyl)propane-1, 3-diamine]bis(N,N′-dimethylformamide)trinickel(II) N,N′- dimethylfoimamide disolvate


Sari M., Atakol O., Svoboda I., Fuess H.

Acta Crystallographica Section E: Structure Reports Online, cilt.62, sa.3, 2006 (SCI-Expanded) identifier identifier

Özet

The title compound, [Ni3(C17H20N 2O2)2(C2H3O 2)2(C3H7NO)2] ·2C3H7NO, is a centrosymmetric trinuclear nickel(II) complex. The central and terminal nickel(II) atoms have distorted octahedral coordination, the central NiII atom by six O atoms, and the terminal NiII atoms by four O atoms and two N atoms each. The average Ni-O and Ni-N distances for the terminal Ni ions are 2.062 (17) and 2.082 (2) Å, respectively. The Ni⋯Ni distance is 3.035 (2) Å. © 2006 International Union of Crystallography All rights reserved.