Structure of N-(2-thiophenyl)-salicylaldimino-diethylamino nickel(II) complex


Elerman Y., Kabak M., Svoboda I.

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, vol.26, no.1, pp.29-32, 1996 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 26 Issue: 1
  • Publication Date: 1996
  • Doi Number: 10.1007/bf02018693
  • Journal Name: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.29-32
  • Keywords: Schiff base, diethylamine, saliclyaldimine, CRYSTAL-STRUCTURE
  • Ankara University Affiliated: No

Abstract

N-(2-thiophenyl)-salicylaldimino-diethylamino nickel(II) complex crystallizes in the orthorhombic crystal system with a = 19.089(4), b = 14.268(7), c = 12.091(4) Angstrom, space group Pbca, Z = 8, and D-x = 1.449 g cm(-3). The central nickel atom is coordinated with S, O, and N atoms. The coordination plane is nearly planar and nearly perpendicular to the diethylamine plane which consist of N(2), C(14), C(15), C(16), and C(17).