Use of deep eutectic solvents as catalyst: A mini-review

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ÜNLÜ BÜYÜKTOPCU A. E., Arikaya A., Takac S.

GREEN PROCESSING AND SYNTHESIS, cilt.8, sa.1, ss.355-372, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Derleme
  • Cilt numarası: 8 Sayı: 1
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1515/gps-2019-0003
  • Dergi Adı: GREEN PROCESSING AND SYNTHESIS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.355-372
  • Anahtar Kelimeler: deep eutectic solvents, Bronsted acid, Lewis acid, catalysis, SURFACTANT-COMBINED CATALYST, 30-PERCENT HYDROGEN-PEROXIDE, ACIDIC IONIC LIQUIDS, ONE-POT, BIODIESEL PRODUCTION, HIGHLY EFFICIENT, MANNICH REACTION, LIGNOCELLULOSIC BIOMASS, CHOLINE CHLORIDE/UREA, GREEN METHOD
  • Ankara Üniversitesi Adresli: Evet

Özet

Deep eutectic solvents (DESs) exhibit numerous advantages over conventional ones used in several chemical and biochemical processes. Besides addressing most of the principles of green chemistry, DESs can also act as catalyst depending on their nature. The use of DESs as acid catalyst has several advantages such as utilization at stoichiometric amount, non-toxicity, possibility of the recovery, similar or higher catalytic effect than the acid itself alone, the recyclability and reusability without a significant loss of activity. In this mini-review, the state-of-the-art in the use of DESs as catalyst is presented. The DESs, which show Lewis type acidity, Bronsted type acidity and other types of catalytic influence in various types of reactions including esterification, organic synthesis, glycolysis and depolymerisation are presented and their roles in the reactions are discussed.