Some Complexes of Nickel(II) with Ono Type Schiff Bases and Their Monodentate Monoligand Adducts Part I.

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Atıf İçin Kopyala

GUNDUZ T., ATAKOL O.

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.19, sa.5, ss.441-451, 1989 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 19 Sayı: 5
• Basım Tarihi: 1989
• Doi Numarası: 10.1080/00945718908048083
• Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.441-451
• Ankara Üniversitesi Adresli: Evet

Özet

Nickel(II) forms complexes of formula NiL with the ONO Schiff bases, N-(2~hydroxyphenyl) salicylaldimine (SAP), N-(2-hydroxy-1-naphthyl) salicylaldimine (SAN) and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine (NAP), but not with N-(2-hydroxy-1-naphthyl)-2-hydroxy-1-naphthylaldimine (NAN). The complexes are yellow and have two unpaired electrons. They are believed to be polymeric and con - tain pseudo-octahedral Ni(II). The complexes react reversibly with certain monodentate nitrogen donors (L1) to form adducts of the formulae NiLL1 (L1= ammonia and piperidine) which are diamagnetic and probably contain square-planar Ni(II). © 1989, Taylor & Francis Group, LLC. All rights reserved.