Spectroscopic study and structure of (E)-2-[(2-chlorobenzylimino)methyl] methoxyphenol

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ÜNVER H., YILDIZ M., ÖZAY H., Durlu T. N.

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, vol.74, no.5, pp.1095-1099, 2009 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 74 Issue: 5
• Publication Date: 2009
• Doi Number: 10.1016/j.saa.2009.09.014
• Journal Name: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.1095-1099
• Keywords: Crystal structure, FT-IR, NMR, Spectroscopic studies, UV-vis
• Ankara University Affiliated: Yes

Abstract

(E)-2-[(2-Chlorobenzylimino)methyl]methoxyphenol has been synthesized from the reaction of 2-hydroxy-3-methoxy-1-benzaldehyde(o-vanillin) with 2-chlorobenzylamine. The title compound has been characterized by using elemental analysis, FT-IR, 1H NMR, 13C NMR and UV-vis spectroscopic techniques. The crystal structure of the title compound has also been examined cyrstallographically. It crystallizes in the orthorhombic space group Pbca with unit cell parameters: a = 7.208(1) A, b = 13.726(2) A, c = 27.858(4) A, V = 2756.0(1)A3, Dc =1.18gcm-3 and Z = 8. The crystal structure was solved by direct methods and refined by full-matrix least squares to a find R = 0.046 for 2773 observed reflections. © 2009 Elsevier B.V. All rights reserved.