Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases

Yıldız E., Pepe Y., Erdener D., Karatay A., Boyacıoğlu B., Ünver H., ...Daha Fazla

JOURNAL OF MOLECULAR STRUCTURE, cilt.1286, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1286
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.molstruc.2023.135611
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Anahtar Kelimeler: Biological activity, Colorimetric sensor, DFT, Femtosecond transient absorption spectroscopy, Schiff base, Sodium 2-formylbenzenesulfonate
  • Ankara Üniversitesi Adresli: Evet

Özet

In this study, 2-formylbenzenesulfonic acid sodium salt-based Schiff bases were synthesized from the reactions of 2-formylbenzenesulfonic acid sodium salt with 2-amino-4-chlorophenol and 2-amino-4-methylphenol. The structure of the compounds was determined by FTIR, UV-Vis and NMR spectroscopy methods using both experimental and DFT methods. The anion sensor properties of the compounds were investigated both UV-Vis spectroscopically and calorimetrically. In addition, the antimicrobial activities, interactions with DNA, DNA cleavage and antioxidant activities of Schiff bases were investigated. Additionally, the effects of group electronegativity on the spectroscopic, biological, chromogenic sensing and optical properties of chlorine and methyl side groups and sodium 2-sulfobenzalidene-aminophenol-based Schiff bases were investigated.