Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases

Yıldız E., Pepe Y., Erdener D., Karatay A., Boyacıoğlu B., Ünver H., ...More

JOURNAL OF MOLECULAR STRUCTURE, vol.1286, 2023 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1286
  • Publication Date: 2023
  • Doi Number: 10.1016/j.molstruc.2023.135611
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Keywords: Biological activity, Colorimetric sensor, DFT, Femtosecond transient absorption spectroscopy, Schiff base, Sodium 2-formylbenzenesulfonate
  • Ankara University Affiliated: Yes

Abstract

In this study, 2-formylbenzenesulfonic acid sodium salt-based Schiff bases were synthesized from the reactions of 2-formylbenzenesulfonic acid sodium salt with 2-amino-4-chlorophenol and 2-amino-4-methylphenol. The structure of the compounds was determined by FTIR, UV-Vis and NMR spectroscopy methods using both experimental and DFT methods. The anion sensor properties of the compounds were investigated both UV-Vis spectroscopically and calorimetrically. In addition, the antimicrobial activities, interactions with DNA, DNA cleavage and antioxidant activities of Schiff bases were investigated. Additionally, the effects of group electronegativity on the spectroscopic, biological, chromogenic sensing and optical properties of chlorine and methyl side groups and sodium 2-sulfobenzalidene-aminophenol-based Schiff bases were investigated.