Syntheses and spectroscopic investigations of 2-pyridyl(N/N)spirocyclotriphosphazenes

Creative Commons License

Elmas G.

Journal of the Turkish Chemical Society, Section A: Chemistry, cilt.5, sa.2, ss.621-634, 2018 (Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 5 Sayı: 2
  • Basım Tarihi: 2018
  • Doi Numarası: 10.18596/jotcsa.379971
  • Dergi Adı: Journal of the Turkish Chemical Society, Section A: Chemistry
  • Derginin Tarandığı İndeksler: Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.621-634
  • Anahtar Kelimeler: 2-Pyridyl(N/N)spirocyclotriphosphazenes, Replacement reactions, Spectroscopy
  • Ankara Üniversitesi Adresli: Evet

Özet

© 2018, Turkish Chemical Society. All rights reserved.The Cl substitution reaction of N3P3Cl6 (1) with N-(2-pyridyl)-methyl-N'-methylpropane-1,3-diamine (2) afforded the partly substituted 2-pyridyl(N/N)spirocyclotriphosphazene (3) (with a yield of 57%) in dry THF. When the Cl replacement reactions of 2 carried out with excess pyrrolidine, morpholine, and 1,4-dioxa-8-azaspiro[4,5]decane (DASD), the corresponding 2-pyridyl(N/N)spirotetrapyrrolidino (3a), tetramorpholino (3b) and tetra(1,4-dioxa-8-azaspiro[4,5]decano) (3c) cyclotriphosphazenes were prepared in moderate yields. The structures of four cyclotriphosphazene derivatives were elucidated by the elemental analyses, Fourier transform infrared (FTIR), heteronuclear mass spectrometry (ESI-MS), heteronuclear multiple-bond correlation (HMBC), single quantum coherence (HSQC),1H,13C, and31P NMR techniques.