{4-methyl-2-[(2-oxidobenzylidene)amino]-phenolato(2-)-N,O,O′} (piperidine-N)-nickel(II)

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Atakol O., KENAR A., Ercan F., Sari M., Yagbasan R.

Acta Crystallographica Section C: Crystal Structure Communications, vol.52, no.8, pp.1881-1884, 1996 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 52 Issue: 8
• Publication Date: 1996
• Doi Number: 10.1107/s0108270196003484
• Journal Name: Acta Crystallographica Section C: Crystal Structure Communications
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
• Page Numbers: pp.1881-1884
• Ankara University Affiliated: Yes

Abstract

In the title compound, [Ni(C14H11NO2)(C5H11N)], the coordination geometry at the Ni atom was found to be a slightly distorted square-planar polygon formed by the O, N and O′ donor atoms of the tridentate ligand and the N donor atom of the monodentate ligand [O-Ni-N 86.6 (2)-95.9 (3)°, Ni-O 1.810 (5) and 1.833 (4), Ni-N 1.862 (6) and 1.933 (7) Å]. The diamagnetic properties of the complex, determined by the Gouy method, are in agreement with the planar coordination.