Photocatalytic degradation of ibuprofen and naproxen in water over NS-TiO2 coating on polycarbonate: Process modeling and intermediates identification


Eslami A., Amini M. M., Asadi A., Safari A. A., DAĞLIOĞLU N.

INORGANIC CHEMISTRY COMMUNICATIONS, cilt.115, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 115
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.inoche.2020.107888
  • Dergi Adı: INORGANIC CHEMISTRY COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, DIALNET
  • Anahtar Kelimeler: Ibuprofen, Naproxen, NS-TiO2, Coating, Polycarbonate, RSM, NONSTEROIDAL ANTIINFLAMMATORY DRUGS, TIO2, OPTIMIZATION, PHARMACEUTICALS, ANTIBIOTICS, TRANSPARENT, PERFORMANCE, ENVIRONMENT, REMOVAL, UV
  • Ankara Üniversitesi Adresli: Hayır

Özet

Nitrogen and sulfur doped TiO2 was coated on polycarbonate (NS-TiO2@PC) by simple deposition method. The coated film was characterized by field emission scanning electron microscope and atomic force microscope. The photocatalytic activity of the NS-TiO2@PC was evaluated through degradation of ibuprofen and naproxen under visible light irradiation. Optimization results showed that the maximal degradation efficiencies of 83% and 100% were achieved for ibuprofen and naproxen, respectively. In addition, the possible photodegradation intermediates were identified by liquid chromatography-mass spectrometry. This study proved that the NSTiO2@PC had excellent stability during photodegradation of pollutants and will have practical applications for environmental remediation.