Preparation of primary arylamines via arylzinc chlorides in good yields

Daskapan T.

TETRAHEDRON LETTERS, vol.47, no.17, pp.2879-2881, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 47 Issue: 17
  • Publication Date: 2006
  • Doi Number: 10.1016/j.tetlet.2006.02.129
  • Journal Name: TETRAHEDRON LETTERS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2879-2881
  • Keywords: electrophilic amination, organozinc reagents, oxime, arylamines, CATALYZED ELECTROPHILIC AMINATION, NITROGEN, AMINES
  • Ankara University Affiliated: Yes

Abstract

Primary arylamines can be prepared easily by electrophilic amination of arylzinc chlorides with acetone 0-(2,4,6-tri-methylphenylsulfonyl)oxime in the presence of DMPU as additive and CuCN as catalyst in good yields. (c) 2006 Elsevier Ltd. All rights reserved.