Accelerating ligands for osmium tetraoxide catalyzed racemic dihydroxylation of alpha-pinene

Erdik E., KAHYA N. D., Daskapan T.

SYNTHETIC COMMUNICATIONS, vol.28, no.1, pp.1-7, 1998 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 28 Issue: 1
  • Publication Date: 1998
  • Doi Number: 10.1080/00397919808005067
  • Journal Name: SYNTHETIC COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1-7
  • Ankara University Affiliated: Yes

Abstract

Osmium tetraoxide catalyzed racemic cis-dihydroxylation of alpha-pinene usinf N-oxide as cooxidant and hexamethylenetetraamine as accelerating ligand in tert-butyl alcohol gives excellent yield of alpha-pinanediol.