Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)

ASMAFİLİZ N., ELMAS G., OKUMUŞ A., BİLGE KOÇAK S., Kilic Z.

TURKISH JOURNAL OF CHEMISTRY, cilt.44, sa.3, ss.543-558, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 3
  • Basım Tarihi: 2020
  • Doi Numarası: 10.3906/kim-1909-83
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.543-558
  • Anahtar Kelimeler: spirocyclic Ferrocenyl phosphazene, (31) P NMR, X-ray crystallography, endocyclic bond angle, exocyclic bond angle, electron density transfer parameter, DNA INTERACTIONS, CYTOTOXIC ACTIVITIES, ANSA-SPIRO, ELECTROCHEMICAL INVESTIGATIONS, ANTIMICROBIAL ACTIVITIES, STEREOGENIC PROPERTIES, BIOLOGICAL-ACTIVITIES, CRYSTAL-STRUCTURES, ELECTRONIC-STRUCTURE, CYCLOTRIPHOSPHAZENE
  • Ankara Üniversitesi Adresli: Evet

Özet

The results of a systematic study of spiro-cyclotri/tetraphosphazenes with ferrocenyl pendant arm on the basis of correlation between structural parameters were presented. The main parameters were obtained from Xray crystallography and (31) P NMR results in order to investigate the relationship between the d P spiro shift values and endocyclic and exocyclic NPN bond angles, and electron density transfer parameters. Structural parameters derived from 11 types of the ferrocenyl cyclophosphazene derivatives with 5- to 7-membered spiro-rings introduced to the literature from our research group were studied and compared with each other.