Simple preparation of surface molecularly imprinted polymer based on silica particles for trace level assay of bisphenol F

KAYA S., Corman M. E., UZUN L., ÖZKAN S. A.

Analytical and Bioanalytical Chemistry, vol.414, no.19, pp.5793-5803, 2022 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 414 Issue: 19
  • Publication Date: 2022
  • Doi Number: 10.1007/s00216-022-04142-z
  • Journal Name: Analytical and Bioanalytical Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Food Science & Technology Abstracts, MEDLINE, Metadex, Pollution Abstracts, Veterinary Science Database, DIALNET, Civil Engineering Abstracts
  • Page Numbers: pp.5793-5803
  • Keywords: Bisphenol F, Molecularly imprinted polymer, Tetraethyl orthosilicate, Porous interface, Electrochemical determination, Sensor, ELECTROCHEMICAL SENSOR, AF
  • Ankara University Affiliated: Yes


© 2022, Springer-Verlag GmbH Germany, part of Springer Nature.A new electrochemical sensor based on molecularly imprinted tetraethyl orthosilicate (TEOS)-based porous interface was developed for selective recognition of bisphenol F (BPF) in this study. The sensor was prepared by depositing the solution containing TEOS and L-tryptophan (L-Trp) in the presence of cetyltrimethylammonium bromide (CTAB) as a pore-maker via hydrolysis/condensation reaction on the glassy carbon electrode (GCE). While the surface morphology and structure characterization were carried out using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), electrochemical characterization was performed through electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The resulted MIP(TEOS:L-Trp)@GCE achieved a wide linear range of 1 × 10−15–1 × 10−14 M for BPF detection with an excellent detection limit of 0.291 fM. Furthermore, the recovery of BPF from spiked bottled water and serum samples varied between 98.83 and 101.03%. These results demonstrate that MIP(TEOS:L-Trp)@GCE was found to be a simple, sensitive, and selective smart interface to detect trace pollution even from complicated samples. Graphical abstract: [Figure not available: see fulltext.].