Köysüren Ö. (Yürütücü), Köysüren H. N., Yağlıkçı S., Tunçel B.
TÜBİTAK Uluslararası İkili İşbirliği Projesi, 2023 - 2024
Turkey and Albania are located in an
advantageous position in the southern part of Europe in terms of the solar
energy. Both countries can receive the solar light with a high intensity
(~1500 kWh/m2) when compared with the most of the European
countries. However, the installed PV capacity of Turkey (5 GW) and Albania
(10 MW) is low compared to the European countries. Although Germany can
receive the solar light with a low intensity of around 900 kWh/m2,
the installed PV capacity has reached to about 49 GW in 2019. The installed PV
capacities of both countries can only cover 2.5% of Turkey’s electricity need
and 1% of Albania’s electricity need. In addition, both countries meet the
majority of their energy needs from foreign countries, which means that both
countries need to increase the installed capacity of the PV systems and
maintain the efficiency of the existing PV systems to able to benefit more from
the sunlight. With the proposed project, it is planned to
develop self-cleaning coatings for the PV systems. If the project is accepted
and completed successfully, the contamination-induced efficiency loss of the
existing PV systems and the PV systems to be produced can be prevented or the
contamination effect on the efficiency loss can be reduced. The acceptance and successful completion of the
project will bring a lot of economic benefits to both countries. The research
groups from both countries have a deep knowledge on the materials science and
its application. The success of their previous studies in the field of
materials science shows the potential for successful completion of this
project. The majority of the works planned within the scope
of the project will be carried out in both countries in partnership. Task 1
will be carried out jointly in coordination. A certain part of Task 2 will be
carried out by the research group in Turkey and another part by the other research
group in Albania. The accumulation of pollution and any kinds of contamination on the
glass cover of the solar cell affects the efficiency of the photovoltaic (PV)
systems. The contamination of the glass cover can absorb and reflect a
certain part of the sunlight irradiation, which can decrease the intensity of
the light coming in through the glass cover. The contamination on the cover
glass of the PV panel has a negative effect on the economic return of the PV
systems. The conversion efficiency from the solar energy to the electrical
energy reduces and the contamination causes additional maintenance and
cleaning costs. Depending on the intensity and the thickness of the
contamination on the cover glass, there might be a 10-20% efficiency loss due
the contamination. In the scope of the project, SiO2/WO3 and SiO2/WO3/ZnO
composites will be coated from their solutions on the glass substrates. The
boron doping will be applied to WO3 to produce the SiO2/WO3-B
and SiO2/WO3-B/ZnO composites. SiO2 has been
selected as the composite constituent owing to its low refractive index and
low surface scattering, which is important in terms of the light
transmittance through the cover glass of the solar cell. SiO2 is
also a hydrophilic semiconductor, which can contribute to the photoinduced
hydrophilicity of the photocatalyst semiconductor. On the other hand, WO3
has been selected as a photocatalyst semiconductor. Under the UV light
irradiation, WO3 can absorb the photons of the UV light,
generating the photoinduced charge carriers. The photoexcited charge carriers
provide both the photoinduced hydrophilicity on the surface of the coating
and the photocatalytic degradation of the organic contaminants accumulated on
the surface of the coating, which allows water droplets to spread and flow on
the surface of the cover glass to remove the contaminations. However, the
recombination rate of the photoexcited charge carriers on the photocatalyst
semiconductor is mostly high. In order to suppress the recombination of the
photoinduced charge carriers, WO3 will be combined with SiO2
or doped with boron atoms. Both effects are expected to reduce the recombination
rate of WO3. Although SiO2 has superior features in
terms of the light transmission, it is not very effective under UV light as a
photocatalyst. The widely preferred photocatalyst ZnO will also be added to
the SiO2/WO3 composite structure to reduce the
recombination rate of WO3 and support its photocatalytic activity. |