2,4-[2,2'-Methylenebis(4-nitrophenoxy)]-2,4,6,6-tetrachlorocyclo-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphazatriene (ansa)

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Copy For Citation

Hokelek T., Akduran N., Yildiz M., Dal H., Kilic Z.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, vol.56, pp.90-92, 2000 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 56
• Publication Date: 2000
• Doi Number: 10.1107/s0108270199012986
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Compendex, EMBASE, INSPEC, MEDLINE
• Page Numbers: pp.90-92
• Ankara University Affiliated: No

Abstract

The title compound, C13H8C14N5O6P3, consists Of a non-planar trimeric phosphazene ring and a bulky 2,2'-methylenebis(4-nitrophenoxy) side group which predominantly determines the molecular shape. With respect to the corresponding values in the reference compound N3P3Cl6, the endocyclic angle around one P atom is the same, but the exocyclic angle is increased, while the endocyclic and exocyclic angles about another P atom are both decreased. This situation is different from that in other reported phosphazene derivatives.